Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH3]3

Muhammad Kaleem Khosa; Muhammad Mazhar; Saqib Ali; Sarim Dastgir; Masood Parvez; Abdul Malik

doi:10.2298/JSC0610001K

Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph ₃GeCH(n-C₃H₇)CH₂CO ₂]Sn[CH₃]₃

Muhammad Kaleem Khosa, Muhammad Mazhar^*, Saqib Ali, Sarim Dastgir, Masood Parvez, Abdul Malik

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR ( ¹H, ¹³C, ¹¹⁹Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph ₃GeCH(n-C₃H₇)CH₂CO ₂]Sn[CH ₃]₃, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity.

Original language	English
Pages (from-to)	1001-1013
Number of pages	13
Journal	Journal of the Serbian Chemical Society
Volume	71
Issue number	10
DOIs	https://doi.org/10.2298/JSC0610001K
Publication status	Published - 2006
Externally published	Yes

Keywords

Bioactivity
Organogermanium
Organotin(IV) carboxylates
Spectroscopy
X-ray structure

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10.2298/JSC0610001K

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@article{46da4e3e96914678883135766efc50ea,

title = "Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH3]3",

abstract = "Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR ( 1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH 3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity.",

keywords = "Bioactivity, Organogermanium, Organotin(IV) carboxylates, Spectroscopy, X-ray structure",

author = "Khosa, \{Muhammad Kaleem\} and Muhammad Mazhar and Saqib Ali and Sarim Dastgir and Masood Parvez and Abdul Malik",

year = "2006",

doi = "10.2298/JSC0610001K",

language = "English",

volume = "71",

pages = "1001--1013",

journal = "Journal of the Serbian Chemical Society",

issn = "0352-5139",

publisher = "Serbian Chemical Society",

number = "10",

}

Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph ₃GeCH(n-C₃H₇)CH₂CO ₂]Sn[CH₃]₃. / Khosa, Muhammad Kaleem; Mazhar, Muhammad; Ali, Saqib et al.
In: Journal of the Serbian Chemical Society, Vol. 71, No. 10, 2006, p. 1001-1013.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium

T2 - X-ray study of [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH3]3

AU - Khosa, Muhammad Kaleem

AU - Mazhar, Muhammad

AU - Ali, Saqib

AU - Dastgir, Sarim

AU - Parvez, Masood

AU - Malik, Abdul

PY - 2006

Y1 - 2006

N2 - Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR ( 1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH 3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity.

AB - Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR ( 1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph 3GeCH(n-C3H7)CH2CO 2]Sn[CH 3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity.

KW - Bioactivity

KW - Organogermanium

KW - Organotin(IV) carboxylates

KW - Spectroscopy

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/33846293218

U2 - 10.2298/JSC0610001K

DO - 10.2298/JSC0610001K

M3 - Article

AN - SCOPUS:33846293218

SN - 0352-5139

VL - 71

SP - 1001

EP - 1013

JO - Journal of the Serbian Chemical Society

JF - Journal of the Serbian Chemical Society

IS - 10

ER -

Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph ₃GeCH(n-C₃H₇)CH₂CO ₂]Sn[CH₃]₃

Abstract

Keywords

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