Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Jameel Al Thagfi; Sarim Dastgir; Alan J. Lough; Gino G. Lavoie

doi:10.1021/om100321n

Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Jameel Al Thagfi
, Sarim Dastgir
, Alan J. Lough
, Gino G. Lavoie

York University Toronto
University of Toronto

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

Original language	English
Pages (from-to)	3133-3138
Number of pages	6
Journal	Organometallics
Volume	29
Issue number	14
DOIs	https://doi.org/10.1021/om100321n
Publication status	Published - 26 Jul 2010
Externally published	Yes

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10.1021/om100321n

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title = "Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands",

abstract = "A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.",

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T1 - Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

AU - Al Thagfi, Jameel

AU - Dastgir, Sarim

AU - Lough, Alan J.

AU - Lavoie, Gino G.

PY - 2010/7/26

Y1 - 2010/7/26

N2 - A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

AB - A new class of bis(acyclic imino)-N-heterocyclic carbene (NCN pincer) ligand precursors was synthesized and structurally characterized. In situ deprotonation using a basic metal precursor resulted in the corresponding copper(I) complexes in good yields. Monometallic and bimetallic structures were observed in the solid state depending on the ligand substitution pattern.

UR - https://www.scopus.com/pages/publications/77955856019

U2 - 10.1021/om100321n

DO - 10.1021/om100321n

M3 - Article

AN - SCOPUS:77955856019

SN - 0276-7333

VL - 29

SP - 3133

EP - 3138

JO - Organometallics

JF - Organometallics

IS - 14

ER -

Synthesis and structural characterization of the first copper(I) complexes with bis(imino)-N-heterocyclic carbene NCN pincer ligands

Abstract

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