Synthesis and self-assembly of polymers containing dicarboximide groups by living ring-opening metathesis polymerization

Jake Dalphond; Hassan S. Bazzi; Kenza Kahrim; Hanadi F. Sleiman

doi:10.1002/1521-3935(200209)203:13<1988::AID-MACP1988>3.0.CO;2-R

Synthesis and self-assembly of polymers containing dicarboximide groups by living ring-opening metathesis polymerization

Jake Dalphond, Hassan S. Bazzi, Kenza Kahrim, Hanadi F. Sleiman

McGill University

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Polymers with narrow molecular weight distributions and controlled architectures were generated by living ring-opening metathesis polymerization of exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide. The dicarboximie units have been previously shown to exhibit biological activity, can selectively bind to the nucleic acid base adenine by hydrogen-bonding, and are readily functionalizable. Block copolymers containing these moieties were generated, and underwent self-assembly into nanoscale spherical aggregates, with surface localized molecular recognition motifs.

Original language	English
Pages (from-to)	1988-1994
Number of pages	7
Journal	Macromolecular Chemistry and Physics
Volume	203
Issue number	13
DOIs	https://doi.org/10.1002/1521-3935(200209)203:13<1988::AID-MACP1988>3.0.CO;2-R
Publication status	Published - 10 Oct 2002
Externally published	Yes

Keywords

Block copolymers
Micelles
Molecular recognition
ROMP
Self-assembly

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10.1002/1521-3935(200209)203:13<1988::AID-MACP1988>3.0.CO;2-R

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abstract = "Polymers with narrow molecular weight distributions and controlled architectures were generated by living ring-opening metathesis polymerization of exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide. The dicarboximie units have been previously shown to exhibit biological activity, can selectively bind to the nucleic acid base adenine by hydrogen-bonding, and are readily functionalizable. Block copolymers containing these moieties were generated, and underwent self-assembly into nanoscale spherical aggregates, with surface localized molecular recognition motifs.",

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T1 - Synthesis and self-assembly of polymers containing dicarboximide groups by living ring-opening metathesis polymerization

AU - Dalphond, Jake

AU - Bazzi, Hassan S.

AU - Kahrim, Kenza

AU - Sleiman, Hanadi F.

PY - 2002/10/10

Y1 - 2002/10/10

N2 - Polymers with narrow molecular weight distributions and controlled architectures were generated by living ring-opening metathesis polymerization of exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide. The dicarboximie units have been previously shown to exhibit biological activity, can selectively bind to the nucleic acid base adenine by hydrogen-bonding, and are readily functionalizable. Block copolymers containing these moieties were generated, and underwent self-assembly into nanoscale spherical aggregates, with surface localized molecular recognition motifs.

AB - Polymers with narrow molecular weight distributions and controlled architectures were generated by living ring-opening metathesis polymerization of exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide. The dicarboximie units have been previously shown to exhibit biological activity, can selectively bind to the nucleic acid base adenine by hydrogen-bonding, and are readily functionalizable. Block copolymers containing these moieties were generated, and underwent self-assembly into nanoscale spherical aggregates, with surface localized molecular recognition motifs.

KW - Block copolymers

KW - Micelles

KW - Molecular recognition

KW - ROMP

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/0037057806

U2 - 10.1002/1521-3935(200209)203:13<1988::AID-MACP1988>3.0.CO;2-R

DO - 10.1002/1521-3935(200209)203:13<1988::AID-MACP1988>3.0.CO;2-R

M3 - Article

AN - SCOPUS:0037057806

SN - 1022-1352

VL - 203

SP - 1988

EP - 1994

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 13

ER -

Synthesis and self-assembly of polymers containing dicarboximide groups by living ring-opening metathesis polymerization

Abstract

Keywords

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