Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Mohammed Al-Hashimi; John G. Labram; Scott Watkins; Majid Motevalli; Thomas D. Anthopoulos; Martin Heeney

doi:10.1021/ol102344m

Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Mohammed Al-Hashimi
, John G. Labram
, Scott Watkins
, Majid Motevalli
, Thomas D. Anthopoulos
, Martin Heeney^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors.

Original language	English
Pages (from-to)	5478-5481
Number of pages	4
Journal	Organic Letters
Volume	12
Issue number	23
DOIs	https://doi.org/10.1021/ol102344m
Publication status	Published - 3 Dec 2010
Externally published	Yes

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10.1021/ol102344m

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title = "Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers",

abstract = "The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors.",

author = "Mohammed Al-Hashimi and Labram, \{John G.\} and Scott Watkins and Majid Motevalli and Anthopoulos, \{Thomas D.\} and Martin Heeney",

year = "2010",

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doi = "10.1021/ol102344m",

language = "English",

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issn = "1523-7060",

publisher = "American Chemical Society",

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T1 - Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

AU - Al-Hashimi, Mohammed

AU - Labram, John G.

AU - Watkins, Scott

AU - Motevalli, Majid

AU - Anthopoulos, Thomas D.

AU - Heeney, Martin

PY - 2010/12/3

Y1 - 2010/12/3

N2 - The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors.

AB - The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d'] bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and demonstrated semiconducting behavior in organic field effect transistors.

UR - https://www.scopus.com/pages/publications/78650378397

U2 - 10.1021/ol102344m

DO - 10.1021/ol102344m

M3 - Article

AN - SCOPUS:78650378397

SN - 1523-7060

VL - 12

SP - 5478

EP - 5481

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

Synthesis and characterization of fused pyrrolo[3,2- d:4,5- d' ]bisthiazole-containing polymers

Abstract

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