Rare and unexpected coordination to copper(II) by a tertiary amide in a macrocyclic ligand

Kevin F. Sibbons; Mohammed Al-Hashimi; Majid Motevalli; Joanna Wolowska; Michael Watkinson

doi:10.1039/b410525g

Rare and unexpected coordination to copper(II) by a tertiary amide in a macrocyclic ligand

Kevin F. Sibbons, Mohammed Al-Hashimi, Majid Motevalli, Joanna Wolowska, Michael Watkinson^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Incorporation of a tertiary amide donor within the framework of a C ₂-symmetric analogue of 1,4,7-triazacyclononane derived from L-valine results in the isolation of a very rare example of a classical Werner copper(II) complex in which tertiary amide coordination occurs; despite the monomeric nature of the complex in the solid state, frozen solution EPR studies reveal the presence of a triplet ground state consistent with a dimeric species.

Original language	English
Pages (from-to)	3163-3165
Number of pages	3
Journal	Dalton Transactions
Issue number	20
DOIs	https://doi.org/10.1039/b410525g
Publication status	Published - 21 Oct 2004
Externally published	Yes

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abstract = "Incorporation of a tertiary amide donor within the framework of a C 2-symmetric analogue of 1,4,7-triazacyclononane derived from L-valine results in the isolation of a very rare example of a classical Werner copper(II) complex in which tertiary amide coordination occurs; despite the monomeric nature of the complex in the solid state, frozen solution EPR studies reveal the presence of a triplet ground state consistent with a dimeric species.",

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AU - Sibbons, Kevin F.

AU - Al-Hashimi, Mohammed

AU - Motevalli, Majid

AU - Wolowska, Joanna

AU - Watkinson, Michael

PY - 2004/10/21

Y1 - 2004/10/21

N2 - Incorporation of a tertiary amide donor within the framework of a C 2-symmetric analogue of 1,4,7-triazacyclononane derived from L-valine results in the isolation of a very rare example of a classical Werner copper(II) complex in which tertiary amide coordination occurs; despite the monomeric nature of the complex in the solid state, frozen solution EPR studies reveal the presence of a triplet ground state consistent with a dimeric species.

AB - Incorporation of a tertiary amide donor within the framework of a C 2-symmetric analogue of 1,4,7-triazacyclononane derived from L-valine results in the isolation of a very rare example of a classical Werner copper(II) complex in which tertiary amide coordination occurs; despite the monomeric nature of the complex in the solid state, frozen solution EPR studies reveal the presence of a triplet ground state consistent with a dimeric species.

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U2 - 10.1039/b410525g

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ER -

Rare and unexpected coordination to copper(II) by a tertiary amide in a macrocyclic ligand

Abstract

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