Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Christine E. Welby; Georgina K. Armitage; Harry Bartley; Alessandro Sinopoli; Baljinder S. Uppal; Paul I.P. Elliott

doi:10.1039/c3pp50437a

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

Christine E. Welby
, Georgina K. Armitage
, Harry Bartley
, Alessandro Sinopoli
, Baljinder S. Uppal
, Paul I.P. Elliott^*

^*Corresponding author for this work

University of Huddersfield

Research output: Contribution to journal › Article › peer-review

33 Citations (Scopus)

Abstract

Complexes of the form [Ru(diimine)₂(btz)]²⁺ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) ₂(solvent)₂]²⁺. This journal is

Original language	English
Pages (from-to)	735-738
Number of pages	4
Journal	Photochemical and Photobiological Sciences
Volume	13
Issue number	5
DOIs	https://doi.org/10.1039/c3pp50437a
Publication status	Published - May 2014
Externally published	Yes

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title = "Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes",

abstract = "Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is",

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year = "2014",

month = may,

doi = "10.1039/c3pp50437a",

language = "English",

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AU - Welby, Christine E.

AU - Armitage, Georgina K.

AU - Bartley, Harry

AU - Sinopoli, Alessandro

AU - Uppal, Baljinder S.

AU - Elliott, Paul I.P.

PY - 2014/5

Y1 - 2014/5

N2 - Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is

AB - Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine) 2(solvent)2]2+. This journal is

UR - https://www.scopus.com/pages/publications/84898823331

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DO - 10.1039/c3pp50437a

M3 - Article

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AN - SCOPUS:84898823331

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JF - Photochemical and Photobiological Sciences

IS - 5

ER -

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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