Membrane processes for environmental remediation of nanomaterials: Potentials and challenges

Nanomaterials have gained huge attention with their wide range of applications. This is mainly driven by their unique properties. Nanomaterials include nanoparticles, nanotubes, nanofibers, and many other nanoscale structures have been widely assessed for improving the performance in different applications. However, with the wide implementation and utilization of nanomaterials, another challenge is being present when these materials end up in the environment, i.e. air, water, and soil. Environmental remediation of nanomaterials has recently gained attention and is concerned with removing nanomaterials from the environment. Membrane filtration processes have been widely considered a very efficient tool for the environmental remediation of different pollutants. Membranes with their different operating principles from size exclusions as in microfiltration, to ionic exclusion as in reverse osmosis, provide an effective tool for the removal of different types of nanomaterials. This work comprehends, summarizes, and critically discusses the different approaches for the environmental remediation of engineered nanomaterials using membrane filtration processes. Microfiltration (MF), ultrafiltration (UF), and nanofiltration (NF) have been shown to effectively remove nanomaterials from the air and aqueous environments. In MF, the adsorption of nanomaterials to membrane material was found to be the main removal mechanism. While in UF and NF, the main mechanism was size exclusion. Membrane fouling, hence requiring proper cleaning or replacement was found to be the major challenge for UF and NF processes. While limited adsorption capacity of nanomaterial along with desorption was found to be the main challenges for MF.