External mass transfer during the adsorption of various pollutants onto activated carbon

Gordon McKay*, Murad J. Bino, A. Altememi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

60 Citations (Scopus)

Abstract

A wide range of experimental studies are reported for the adsorption of phenol and p-chlorophenol onto activated carbon-Type Filtrasorb 400-in an agitated batch adsorber. A model has been used to determine the external mass transfer coefficient for the systems and the effect of several experimental variables have been investigated: these include agitation, initial pollutant concentration, carbon mass, carbon particle size and solution temperature. The mass transfer coefficient has been correlated in terms of the dimensionless Sh/Sc0.33 against each variable. The Sherwood number, Sh = kfR/Dmol, relates the external mass transfer coefficient kf to particle radius, R, and molecular diffusivity, Dmol. The Schmidt number, Sc, is the ratio of kinematic viscosity, v, to molecular diffusivity. A few results are also reported for the adsorption of sodium dodecyl sulphate and mercuric ions onto activated carbon.

Original languageEnglish
Pages (from-to)435-442
Number of pages8
JournalWater Research
Volume20
Issue number4
DOIs
Publication statusPublished - Apr 1986
Externally publishedYes

Keywords

  • activated carbon
  • adsorption
  • mass transfer
  • mercury
  • p-chlorophenol
  • phenol
  • sodium dodecyl sulphate

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