Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels: A thermal desorption spectroscopy study

Shabnam Karimi; Iman Taji; Simona Palencsár; Arne Dugstad; Tarlan Hajilou; Afrooz Barnoush; Kim Verbeken; Roy Johnsen; Tom Depover

doi:10.1016/j.corsci.2023.111210

Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels: A thermal desorption spectroscopy study

Shabnam Karimi^*
, Iman Taji
, Simona Palencsár
, Arne Dugstad
, Tarlan Hajilou
, Afrooz Barnoush
, Kim Verbeken
, Roy Johnsen
, Tom Depover

^*Corresponding author for this work

Norwegian University of Science and Technology
Institute for Energy Technology
Ghent University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The hydrogen uptake in three high-strength carbon steels is studied after exposure to three different environments: an aqueous solution with CO₂ bubbling, CO₂/H₂S bubbling, and cathodic charging without external gassing. The hydrogen uptake is substantially higher in CO₂/H₂S environment compared to CO₂ environment for all materials. The lamellar cementite morphology absorbs higher hydrogen than the material with spheroidite microstructure with similar carbon content. The corrosion layer formed on the steels in CO₂ environment strongly affects the hydrogen effusion and the thermal desorption spectroscopy spectrum in all materials, while the corrosion layer formed in CO₂/H₂S environment does not show this effect.

Original language	English
Article number	111210
Journal	Corrosion Science
Volume	219
DOIs	https://doi.org/10.1016/j.corsci.2023.111210
Publication status	Published - 15 Jul 2023

Keywords

CO environment
CO/HS environment
Carbon steel
Pearlite
Spheroidite
Thermal desorption spectroscopy

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10.1016/j.corsci.2023.111210

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Karimi, S., Taji, I., Palencsár, S., Dugstad, A., Hajilou, T., Barnoush, A., Verbeken, K., Johnsen, R., & Depover, T. (2023). Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels: A thermal desorption spectroscopy study. Corrosion Science, 219, Article 111210. https://doi.org/10.1016/j.corsci.2023.111210

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title = "Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels: A thermal desorption spectroscopy study",

abstract = "The hydrogen uptake in three high-strength carbon steels is studied after exposure to three different environments: an aqueous solution with CO2 bubbling, CO2/H2S bubbling, and cathodic charging without external gassing. The hydrogen uptake is substantially higher in CO2/H2S environment compared to CO2 environment for all materials. The lamellar cementite morphology absorbs higher hydrogen than the material with spheroidite microstructure with similar carbon content. The corrosion layer formed on the steels in CO2 environment strongly affects the hydrogen effusion and the thermal desorption spectroscopy spectrum in all materials, while the corrosion layer formed in CO2/H2S environment does not show this effect.",

keywords = "CO environment, CO/HS environment, Carbon steel, Pearlite, Spheroidite, Thermal desorption spectroscopy",

author = "Shabnam Karimi and Iman Taji and Simona Palencs{\'a}r and Arne Dugstad and Tarlan Hajilou and Afrooz Barnoush and Kim Verbeken and Roy Johnsen and Tom Depover",

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T1 - Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels

T2 - A thermal desorption spectroscopy study

AU - Karimi, Shabnam

AU - Taji, Iman

AU - Palencsár, Simona

AU - Dugstad, Arne

AU - Hajilou, Tarlan

AU - Barnoush, Afrooz

AU - Verbeken, Kim

AU - Johnsen, Roy

AU - Depover, Tom

PY - 2023/7/15

Y1 - 2023/7/15

N2 - The hydrogen uptake in three high-strength carbon steels is studied after exposure to three different environments: an aqueous solution with CO2 bubbling, CO2/H2S bubbling, and cathodic charging without external gassing. The hydrogen uptake is substantially higher in CO2/H2S environment compared to CO2 environment for all materials. The lamellar cementite morphology absorbs higher hydrogen than the material with spheroidite microstructure with similar carbon content. The corrosion layer formed on the steels in CO2 environment strongly affects the hydrogen effusion and the thermal desorption spectroscopy spectrum in all materials, while the corrosion layer formed in CO2/H2S environment does not show this effect.

AB - The hydrogen uptake in three high-strength carbon steels is studied after exposure to three different environments: an aqueous solution with CO2 bubbling, CO2/H2S bubbling, and cathodic charging without external gassing. The hydrogen uptake is substantially higher in CO2/H2S environment compared to CO2 environment for all materials. The lamellar cementite morphology absorbs higher hydrogen than the material with spheroidite microstructure with similar carbon content. The corrosion layer formed on the steels in CO2 environment strongly affects the hydrogen effusion and the thermal desorption spectroscopy spectrum in all materials, while the corrosion layer formed in CO2/H2S environment does not show this effect.

KW - CO environment

KW - CO/HS environment

KW - Carbon steel

KW - Pearlite

KW - Spheroidite

KW - Thermal desorption spectroscopy

UR - https://www.scopus.com/pages/publications/85156120096

U2 - 10.1016/j.corsci.2023.111210

DO - 10.1016/j.corsci.2023.111210

M3 - Article

AN - SCOPUS:85156120096

SN - 0010-938X

VL - 219

JO - Corrosion Science

JF - Corrosion Science

M1 - 111210

ER -

Evaluation of microstructural and environmental effects on the hydrogen uptake and desorption in high-strength carbon steels: A thermal desorption spectroscopy study

Abstract

Keywords

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