EPR and optical absorption investigations of photochromic effect in nearly stoichiometric LiNbO3:Fe

M. C. Mozzati*, A. G. Badalyan, G. Demaestri, P. Galinetto, F. Rossella, V. Bermudez, C. B. Azzoni, G. Samoggia

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

EPR and optical absorption measurements have been performed on nearly stoichiometric lithium niobate single crystals with iron in traces and in 0.1% molar nominal amount. Thermal treatments in reducing atmosphere allowed to obtain samples with different Fe2+/Fe3+ ratios. The Fe2+/Fe3+ dynamic has been observed by irradiating the samples with UV and visible light in the temperature range 4-300 K: the photochromic effect resulted to be more evident in the strongly reduced crystals. A simple model to explain the photochromic behavior in nearly stoichiometric LiNbO3:Fe is proposed.

Original languageEnglish
Title of host publicationAdvanced Materials Forum III - Proceedings of the 3rd International Materials Symposium 2005 and 12th Encontro da Sociedade Portuguesa de Materiais - SPM
PublisherTrans Tech Publications Ltd
Pages152-155
Number of pages4
EditionPART 1
ISBN (Print)9780878494026
DOIs
Publication statusPublished - 2006
Externally publishedYes
Event3rd International Materials Symposium and 12th Portuguese Materials Society Meeting 2005 - Aveiro, Portugal
Duration: 20 Mar 200523 Mar 2005

Publication series

NameMaterials Science Forum
NumberPART 1
Volume514-516
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

Conference3rd International Materials Symposium and 12th Portuguese Materials Society Meeting 2005
Country/TerritoryPortugal
CityAveiro
Period20/03/0523/03/05

Keywords

  • Electron paramagnetic resonance
  • Lithium niobate
  • Photochromic effect

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