Effective and stable FeNi@ N-doped graphene counter electrode for enhanced performance dye sensitized solar cells

  • Nasser A.M. Barakat*
  • , M. Shaheer Akhtar
  • , Ibrahim M.A. Mohamed
  • , Yara Abu Dakka
  • , Rawan Hamdan
  • , Ahmed G. El-Deen
  • , Khalid Elsaid
  • , M. Obaid
  • , Saeed Al-Meer
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Citations (Scopus)

Abstract

N-doped FeNi@graphene is introduced as effective and stable non-precious counter electrode for the dye sensitized solar cells. After preparation of graphene oxide using the chemical route, the obtained product has been refluxed in presence of nickel acetate, ferrous acetate and urea at 150 °C for 12 h. Then, the solid product was mixed with melamine and sintered under nitrogen atmosphere at 850 °C. The invoked characterization techniques affirmed formation of N-doped graphene decorated by FeNi bimetallic nanoparticles. In dye sensitized solar cell, the prepared material revealed good performance as counter electrode as the estimated efficiency was 4.12% with a photocurrent and an open circuit voltage of 8.96 mA/cm2 and 0.73 V, respectively, Moreover, the cyclic voltammetry measurements indicated very good catalytic activity and distinct stability.

Original languageEnglish
Pages (from-to)80-84
Number of pages5
JournalMaterials Letters
Volume191
DOIs
Publication statusPublished - 15 Mar 2017
Externally publishedYes

Keywords

  • Counter electrode
  • Decorated graphene
  • Dye sensitized solar cells

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