Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions

Mohammed Al-Hashimi; Asma Qazi; Alice C. Sullivan; John R.H. Wilson

doi:10.1016/j.molcata.2007.07.050

Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions

Mohammed Al-Hashimi
, Asma Qazi
, Alice C. Sullivan^*
, John R.H. Wilson

^*Corresponding author for this work

Queen Mary University of London
PhosphonicS Ltd.

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Novel heterogeneous silica supported 1,2-bis(ethylthio)ethane palladium and 1,2-bis(ethylthio)propane palladium catalysts are reported. Applied to Suzuki coupling chemistry these catalysts are very effective, reusable and resist leaching at room temperature in isopropanol or in hot xylene.

Original language	English
Pages (from-to)	160-164
Number of pages	5
Journal	Journal of Molecular Catalysis A: Chemical
Volume	278
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2007.07.050
Publication status	Published - 14 Dec 2007
Externally published	Yes

Keywords

1,2-Bis(trimethoxysilylethylthio)ethane and 1,2-bis(trimethoxysilylethylthio)propane
Cross-coupling
Di(ethylthio)propane
Dithio palladium
Immobilized di(ethylthio)ethane
Palladium
Silica support
Suzuki

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10.1016/j.molcata.2007.07.050

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title = "Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions",

abstract = "Novel heterogeneous silica supported 1,2-bis(ethylthio)ethane palladium and 1,2-bis(ethylthio)propane palladium catalysts are reported. Applied to Suzuki coupling chemistry these catalysts are very effective, reusable and resist leaching at room temperature in isopropanol or in hot xylene.",

keywords = "1,2-Bis(trimethoxysilylethylthio)ethane and 1,2-bis(trimethoxysilylethylthio)propane, Cross-coupling, Di(ethylthio)propane, Dithio palladium, Immobilized di(ethylthio)ethane, Palladium, Silica support, Suzuki",

author = "Mohammed Al-Hashimi and Asma Qazi and Sullivan, \{Alice C.\} and Wilson, \{John R.H.\}",

year = "2007",

month = dec,

day = "14",

doi = "10.1016/j.molcata.2007.07.050",

language = "English",

volume = "278",

pages = "160--164",

journal = "Journal of Molecular Catalysis A: Chemical",

issn = "1381-1169",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions

AU - Al-Hashimi, Mohammed

AU - Qazi, Asma

AU - Sullivan, Alice C.

AU - Wilson, John R.H.

PY - 2007/12/14

Y1 - 2007/12/14

N2 - Novel heterogeneous silica supported 1,2-bis(ethylthio)ethane palladium and 1,2-bis(ethylthio)propane palladium catalysts are reported. Applied to Suzuki coupling chemistry these catalysts are very effective, reusable and resist leaching at room temperature in isopropanol or in hot xylene.

AB - Novel heterogeneous silica supported 1,2-bis(ethylthio)ethane palladium and 1,2-bis(ethylthio)propane palladium catalysts are reported. Applied to Suzuki coupling chemistry these catalysts are very effective, reusable and resist leaching at room temperature in isopropanol or in hot xylene.

KW - 1,2-Bis(trimethoxysilylethylthio)ethane and 1,2-bis(trimethoxysilylethylthio)propane

KW - Cross-coupling

KW - Di(ethylthio)propane

KW - Dithio palladium

KW - Immobilized di(ethylthio)ethane

KW - Palladium

KW - Silica support

KW - Suzuki

UR - https://www.scopus.com/pages/publications/35748938741

U2 - 10.1016/j.molcata.2007.07.050

DO - 10.1016/j.molcata.2007.07.050

M3 - Article

AN - SCOPUS:35748938741

SN - 1381-1169

VL - 278

SP - 160

EP - 164

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

IS - 1-2

ER -

Dithio palladium modified silicas-New heterogeneous catalysts for Suzuki cross-coupling reactions

Abstract

Keywords

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