Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts

Tatyana V. Khamatnurova; Mitchel Johnson; David Santana; Hassan S. Bazzi; David E. Bergbreiter

doi:10.1007/s11244-014-0315-3

Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts

Tatyana V. Khamatnurova
, Mitchel Johnson
, David Santana
, Hassan S. Bazzi
, David E. Bergbreiter^*

^*Corresponding author for this work

Texas A&M University
Texas A&M University at Qatar

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5-10 mol% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.

Original language	English
Pages (from-to)	1438-1444
Number of pages	7
Journal	Topics in Catalysis
Volume	57
Issue number	17-20
DOIs	https://doi.org/10.1007/s11244-014-0315-3
Publication status	Published - 1 Nov 2014
Externally published	Yes

Keywords

Cross-coupling
Dimethylaminopyridine
Palladium
Phosphine
Recycling
Suzuki

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10.1007/s11244-014-0315-3

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title = "Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts",

abstract = "Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5-10 mol\% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol\% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.",

keywords = "Cross-coupling, Dimethylaminopyridine, Palladium, Phosphine, Recycling, Suzuki",

author = "Khamatnurova, \{Tatyana V.\} and Mitchel Johnson and David Santana and Bazzi, \{Hassan S.\} and Bergbreiter, \{David E.\}",

note = "Publisher Copyright: {\textcopyright} 2014 Springer Science+Business Media New York.",

year = "2014",

month = nov,

day = "1",

doi = "10.1007/s11244-014-0315-3",

language = "English",

volume = "57",

pages = "1438--1444",

journal = "Topics in Catalysis",

issn = "1022-5528",

publisher = "Springer",

number = "17-20",

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TY - JOUR

T1 - Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts

AU - Khamatnurova, Tatyana V.

AU - Johnson, Mitchel

AU - Santana, David

AU - Bazzi, Hassan S.

AU - Bergbreiter, David E.

PY - 2014/11/1

Y1 - 2014/11/1

N2 - Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5-10 mol% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.

AB - Soluble poly(4-alkylstyrene) containing 4-methyl-, 4-tert-butyl, 4-dodecyl-, and 4-octadecylstyrene were formed either with monomers containing dyes-, ligands, or catalysts or with 5-10 mol% of 4-chloromethylstyrene and studied as supports for ligands or catalysts. Studies with dye-labeled polymers showed that polymers containing longer alkyl groups alone or at ca. 10 mol% loading are highly soluble in heptane can be used to separate and recycle organo- and transition metal catalysts.

KW - Cross-coupling

KW - Dimethylaminopyridine

KW - Palladium

KW - Phosphine

KW - Recycling

KW - Suzuki

UR - https://www.scopus.com/pages/publications/84925962085

U2 - 10.1007/s11244-014-0315-3

DO - 10.1007/s11244-014-0315-3

M3 - Article

AN - SCOPUS:84925962085

SN - 1022-5528

VL - 57

SP - 1438

EP - 1444

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 17-20

ER -

Designing Phase Selectively Soluble Polymer-Supports for Dimethylaminopyridine and Phosphine-Ligated Pd(0) Catalysts

Abstract

Keywords

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